3DS CFW Setting comb keys:
Holding (Select) on boot will launch the Luma3DS configuration menu.
Holding (Start) on boot will launch GodMode9, or if you have multiple payloads in /luma/payloads/, the Luma3DS chainloader.
By default, pressing (Left Shoulder) + (Down D-Pad) + (Select) while in 3DS mode will open the Rosalina menu,
where you can check system information, take screenshots, enable cheats, and more. This can be changed from the Rosalina menu.
Holding (Start) + (Select) + (X) on boot will dump boot9.bin, boot11.bin, and otp.bin to the boot9strap folder on your SD card.
Source | Date: February 17th 2022
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